Japan lets you make payments for online content at convenience stores.
How it works is you purchase a product online and it gives you a barcode that can be scanned at any major convenience store. You go to the store, scan the code, hand over cash, and the content you bought is instantly unlocked once the payment is confirmed.
I doubt Mullvad has anywhere near the volume of transaction Valve does. And mullvad has plenty of other payment methods, so only a tiny, tiny fraction of their userbase likely pays in mail-in cash.
I don't think Valve could feasibly implement this at their scale - especially if this method was the _only_ way to acquire the games in question.
This realistically doesn’t work that well above anything like a micro scale. It’s also a crime to mail cash across many borders, so it only really works domestically.