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>. Hence, the Br atoms kept the molecules on track, likely because their interaction with the surface substantially contributed to the barrier for molecular rotation

Yeah that's a reason people prefer AFM (but then they won't be able to do manipulation)?

[Br- is a "good leaving group", not so much at 7K maybe. You are also right in that, above all, they don't want their molecule sticking (irreversibly) to the (tungsten) tip ]






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