Just as a heads up on this, slack doesn't even use HTTPS! Your employer can certainly read all private slacks on your work network, even if it's a non-work-slack workspace
Pretty sure it uses HTTPS, but if you're on a corporate network on corporate hardware, there is a real chance that there's a corporate MITM proxy that is capable of reading all of your HTTPS traffic.
From experience, if the org is doing https mitm then it almost certainly also has network device authentication (eg Cisco ICE) that would only allow corporate whitelisted devices. Usually with custom builds that would already have the corp root cert trusted.